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Ceramic Materials and Bearing Compatibility

Silicon Nitride is an Optimal Rolling Element Material
  Oxides Nitrides Carbides
Al203 Zr203 Si3N4 SiC B4C
Rolling Contact Fatigue Poor Poor Excellent Poor Poor
Density g/cc 3.9 6.1 3.2 3.1 2.5
Flexural Strength, MPa, RT 300-600 900-1200 800-1100 400-600 300-400
Fracture Toughness
MPa-m1/2
3-4 6-10 5-7 3-4 2-3
Thermal Cof. Exp.
(x10-6/°K
7-8 9-11 2-3 4-5 5-6
Hardness, HV (10kg load) 15-18 11-13 15-17 25-27 27-29
Thermal Shock Resistance, ºC Fair Fair Very Good Very Good Excellent


The green text in the chart identifies properties that are desirable in a rolling element such as low density, high hardness, and good fracture toughness. However, only silicon nitride possesses superior performance in rolling contact fatigue (RCF) which is essential to the performance of a rolling element in a bearing. Properties of silicon nitride, other ceramics and steel. Three basic types of ceramics could be considered as bearing ball materials. The carbides are extremely hard and very light materials while the oxides provide very good toughness. However, neither of these materials performs well in rolling contact fatigue, a critical parameter associated with rolling elements in bearings. Silicon nitride possesses high hardness, high stiffness, and low weight compared to steel. Silicon nitride performs much better than steel in rolling contact fatigue making it an ideal rolling element material for bearings. Silicon nitride is significantly harder, has a 60% lower density, and a 50% higher Young's Modulus than typical bearing steels. These properties, combined with a low thermal expansion and low coefficient of friction against steel are essential to improved rolling element performance in a bearing. Rolling contact fatigue (RCF) of nitride and steel A critical performance measure for rolling elements is rolling contact fatigue (RCF) life. This is a statistical measure of rolling element failure and load. While many materials have desirable characteristics (light weight, high hardness, etc), few can withstand the contact stresses imposed internally on a bearing. The rolling contact fatigue life of silicon nitride is far superior to steel. In fact, to create a Weibull plot of Si3N4 similar to the illustration, the stresses must be increased to a level where steel failure is instantaneous.

Si3N4 vs Steel as a Bearing Material

Property Typical Steel CERBEC Si3N4 CERBEC Difference
Density [g/cc] 7.6 3.2 -58% Lighter
Hardness [Vickers] 700 1550 +121% Harder
Elastic Modulus [GPa] 190 320 +68% Stiffer
Thermal Expansion Coefficient (10-6K)
[RT to 800C]
12.3 2.9 -76%
Max Usage Temperature [°C] 320 1000 +680%°C
Surface Finish Grade 5 [micron] 0.02 0.005 +75% Smoother
Material Fatigue, Life Wear Resistance - <10x <10x
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